The bis-urea motif as a tool to functionalize self-assembled nanoribbons.

نویسندگان

  • Matthijn R J Vos
  • Gorka Etxebarria Jardĺ
  • Anna Llanes Pallas
  • Monica Breurken
  • Otto L J van Asselen
  • Paul H H Bomans
  • Phillip E L G Leclère
  • Peter M Frederik
  • Roeland J M Nolte
  • Nico A J M Sommerdijk
چکیده

Here we present a surfactant molecule (1) containing an ammonium headgroup, in which a bis-ureido group is incorporated in its hydrocarbon chain. Due to strong hydrogen bonding interactions, 1 forms well-defined highly ordered ribbon-like aggregates in water. Moreover, we demonstrate that these ribbons can be functionalized via a modular approach through molecular recognition of other bis-urea containing molecules. The dye disperse orange and biotin were coupled to matching bis-ureido groups and incorporated into the ribbon structure. The anchoring of different functionalities in a modular approach proved to be possible using the molecular recognition capabilities of the bis-ureido moiety, thereby opening possibilities to a wide range of applications.

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 127 48  شماره 

صفحات  -

تاریخ انتشار 2005